Dilman Lab (@DilmanLab) profile picture

Dilman Lab

@DilmanLab

Prof. Alexander Dilman's group at the Zelinsky Institute. Our research is focused on organofluorine chemistry and photocatalysis.

 Moscow, Russia
dilmanlab.ru
Joined November 2019
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  • Followers225
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Photo by Dilman Lab (@DilmanLab)Photo by Dilman Lab (@DilmanLab)Photo by Dilman Lab (@DilmanLab)Photo by Dilman Lab (@DilmanLab)
Pyridine meets difluorocarbene. Our paper on synthesis of difluoroalkylated hetarenes is finally online! Please check it out in @JOC_OL #fluorine #carbene #heterocycles bit.ly/3Bg0fx3
Image from Dilman Lab (@DilmanLab)
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Just accepted Update by Alexander D. Dilman and co-authors: Generation of Alkyl #Radicals from #Thiols via #Zinc Thiolates: Application for the Synthesis of gem‐Difluorostyrenes onlinelibrary.wiley.com/doi/…
Image from Adv. Synth. & Catal. (@AdvSynthCatal)
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Just accepted Update by Alexander D. Dilman and co-authors: #Photoredox #Fluoroalkylation of #Hydrazones in Neutral and #Reductive Modes onlinelibrary.wiley.com/doi/…
Image from Adv. Synth. & Catal. (@AdvSynthCatal)
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Visible-light-promoted reversible sulfide/iodide exchange in fluoroalkyl sulfides enabled by electron donor-acceptor complex formation (van der Worp, Kosobokov, Dilman @DilmanLab) onlinelibrary.wiley.com/doi/…
Image from ChemPhotoChem (@ChemPhotoChem)
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Dilman Lab retweeted
Chao Li Lab (@LabChao) profile picture
Chao Li Lab@LabChao24 Feb 2021
After having thought about the dehydoxylative cross-coupling for years (since I was a postdoc in Baran Lab @BaranLabReads), we finally figured out an expedient method @J_A_C_S: pubs.acs.org/doi/10.1021/jac…
Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl...

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl...

Abstract. As alcohols are ubiquitous throughout chemical science, this functional group represents a highly attractive starting material for forging new C–

pubs.acs.org
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Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds by @DilmanLab onlinelibrary.wiley.com/doi/…
Image from Angewandte Chemie (@angew_chem)
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Boramidines are new motifs with potential in many areas. Finding small heterocycles that are stable to water and a wide range of solvents, yet have somehow eluded synthesis, is interesting. @A_Aspuru_Guzik @SeferosGroup pubs.acs.org/doi/10.1021/jac…
Boramidine: A Versatile Structural Motif for the Design of Fluorescent Heterocycles

Boramidine: A Versatile Structural Motif for the Design of Fluorescent Heterocycles

Abstract. Sodium cyanoborohydride-derived N-alkyl­nitrilium­boranes were found to be versatile precursors for the synthesis of novel boron-containing heter

pubs.acs.org
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Dilman Lab retweeted
Au Chem (@gold_chem) profile picture
Au Chem@gold_chem29 Jun 2020
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers @DilmanLab @BeilsteinInst: doi.org/10.3762/bjoc.16.126
Image from Au Chem (@gold_chem)
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ortho-Dialkylamino Arylboranes as Efficient Reagents for Difluorocarbene Trapping : pubs.rsc.org/en/content/arti…
Image from Boron-Chem-Research (@Boron_Chemistry)
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Trapping of Difluorocarbene by Frustrated Lewis Pairs (Dilman) doi.wiley.com/10.1002/anie.2…
Image from Angewandte Chemie (@angew_chem)
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Thank you for highlighting our work.
Boron-Chem-Research (@Boron_Chemistry) profile pictureBoron-Chem-Research@Boron_Chemistry17 Mar 2020
Trapping of Difluorocarbene by Frustrated Lewis Pairs (@DilmanLab): onlinelibrary.wiley.com/doi/…
Image from Boron-Chem-Research (@Boron_Chemistry)
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Acetylene trimerization reported by Berthelot and Zelinsky was finally unveiled. The mistery of self-promoted carbocatalytic synthesis of benzene. @AnanikovLab acspubs.co/Npvk30qhLwM
Image from J. Am. Chem. Soc. (@J_A_C_S)
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Dilman Lab retweeted
nagib lab (@nagiblab) profile picture
nagib lab@nagiblab6 Mar 2020
Double (vicinal) C-H functionalization of alcohols! Check out this cool “reversed” radical/polar crossover mechanism @J_A_C_S by Allen, Raymond, & Ethan! pubs.acs.org/doi/10.1021/jac…
Image from nagib lab (@nagiblab)
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Our latest paper "Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation" is now online @JOC_OL #visiblelight #catalysis #radicals pubs.acs.org/doi/10.1021/acs…
Image from Dilman Lab (@DilmanLab)
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Seeing double👀👀 after new year's revelry🎆? Then please check out our latest publication on dual Cr-photoredox catalysis to access 1,2-amino alcohols, just accepted in @J_A_C_S. #chromium #photoredox #catalysis #aminoalcohols pubs.acs.org/doi/10.1021/jac…
Image from Glorius Group (@GloriusGroup)
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Check out our recent @JOC_OL paper. pubs.acs.org/doi/abs/10.1021… #photoredox #radical #fluorine
Image from Dilman Lab (@DilmanLab)
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Dilman Lab retweeted
Cornellab (@CornellaLab) profile picture
Cornellab@CornellaLab9 Dec 2019
Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 nature.com/articles/s41929-0…
Image from Cornellab (@CornellaLab)
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Check out our new paper – now published in @ChemicalScience ! pubs.rsc.org/en/content/arti… #photoredox #radical #fluorine
Image from Dilman Lab (@DilmanLab)
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Photoredox Catalytic alpha-Alkoxypentafluorosulfanylation of alpha-methyl- and alpha-phenylstyrene using SF6 (Wagenknecht) doi.wiley.com/10.1002/anie.2…
Image from Angewandte Chemie (@angew_chem)
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Our group is now on Twitter! Follow us to know more about our group as well as anything interesting related to organic chemistry.
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