
ALT Graph showing the pressure of vapor-saturation (y-axis) against oxygen fugacity (x-axis) for a Hawaiian tholeiite at 1200 'C with 1000 ppm CO2-eq, 3 wt% H2O-eq, and 1000 ppm S-eq. If there are only oxidised C-O-H species the line is horizontal and hence independent of fO2. If reduced and oxidised C-O-H species are included (but no S), the line starts at the same value as the oxidised C-O-H case at high fO2 but increases with decreasing fO2. If you had S, there is a small maximum in the curve at DFMQ~1. VolatileCalc is similar to the oxidised C-O-H case but at a higher absolute pressure of vapor-saturation. Below, the fO2 of different tectonic settings is shown. The sulfur maximum is in the range of OIB and arc and the reduced fO2 range effects lunar and martian samples.

























