Organic Chemistry Prof, Texas A&M, Isotope Effects, Dynamic Effects, AC Cope Scholar, TAMU AFS Awards In Teaching and Research, Well Fargo Honors Mentor of Year

Joined February 2009
Oh, a related story that I tell: there is a graph in the Jurassic Park book that is completely LOL for anyone who has made a histogram from real data. Crichton liked to pretend he knew science, but actually doing it makes a difference.
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A short science lesson. The histogram of murders vs year in Springfield is indistinguishable from random noise. Any interpretation of this data is the equivalent of seeing a dog in the clouds. For comparison, the graphs I show below are based on a random-number generator.
Replying to @ddale8
So where did he get β€œmurders are up by 81% because of what Kamala Harris has allowed to happen to this small community”? His team says he was comparing…the 2023 # (9 murders) to the 2021 # (5). That’s an 80% increase. But, uh, many issues here: cnn.com/2024/09/20/politics/…
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SchrΓΆdinger's cat RPMD for tunneling through a 0.2 kcal/mol barrier at 10 K, forming the anti-Markovnikov product from BH3 + propene. The part that freaks me is how long tunneling takes, literally hundreds of fs with the H spread out on both sides of the barrier.
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It would take 10 TAs and a classroom with tables that automatically groups people.
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Replying to @leecronin
Those are indeed words there, but if β€œnatural” includes everything humans do, despite its #1 dictionary definition, then the word has no meaning at all. But I suppose Humpty Dumpty apply:
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Replying to @HollandLab_
You should verify my math and attempt to pick holes in it. But I love the word "useful." For thermodynamics, an activity of 1 for pure water making its pKa 14 is most useful. But here is a different question. For dilute MeOH (pKa 15.5) and dilute 18OH2 in water, which is true?
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Ok, just for fun, let's depart into la-la land and choose a different equation that would make the pKa of dilute 18OH2 be 14 instead of 15.7. This equation would work:
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Since it has been asked about, I thought I should expand slightly on an "assumption" here. I don't see this as an assumption at all - I am just counting - but you might say that I am assuming this:
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I demand at least a week of press stories about how conservatives are coming for your dog. Sure, it starts will leash laws, but it’s a slippery slope, and here, you can see, Matt is showing the next big step in their radical agenda. Soon, our friends will be gone forever.
Matt Walsh
@MattWalshBlog10 Jan 2023
Pitbulls should be banned and there is no sane argument to the contrary. They are dangerous animals, responsible for a vastly disproportionate number of fatal maulings in this country. The fact that you think they're cute does not outweigh the danger. Ban them.
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Replying to @drugmonkeyblog
I don’t think the author, or most PIs, understand this. The cause is subtle, and it leads to a lot of wasted effort from PIs. It is also why the rebuttal system proposed by the author mostly wouldn’t work.
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Please please please don’t do this. Yea sure it is bad science, but we say lots of things that are wrong. The important thing is that it is god-awful teaching.
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Still nonsense, but 1000% better than the typical explanation of homeopathic medicine.
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I have been talking with ChapGPT about organic chemistry. No, it never gets anything right, it is gibberish, but very good gibberish. Pretty sure I have seen worse YouTube videos. Scary, if it turns in all of its work it might get a C in my class.
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